For tying off Waldorf/Steiner doll heads, makers typically use a strong, slightly textured linen thread that grips well and won’t slip.
This is the one I have been using for years, I use it doubled.
Available:
5 grams
50 gram spool
Why Linen thread ?
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Very strong natural fibre
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Slight texture grips fabric and grips to itself
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Doesn’t stretch like cotton
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Holds tight whilst sculpting (neck definition, head shaping)